UDK 66 Химическая технология. Химическая промышленность. Родственные отрасли
UDK 60 Прикладные науки. Общие вопросы
The paper presents analytical expressions for the enthalpy of vaporization and the enthalpy of fusion of glycols and glycol ethers obtained by using the theory of similarity. It is shown that the prediction of these parameters allows us to calculate the phase diagrams of liquid-solid and liquid-vapor, and eutectic and azeotrope parameters in systems of glycol ether-water and glycol ether-alkane
Evaporation enthalpy, melting enthalpy, thermodynamic similarity, eutectic, azeotrope
1. Kenisarin, M. Solar energy storage using phase change materials / M. Kenisarin, K. Mahkamov // Renewable and Sustainable Energy Reviews. - 2007. - № 11. - P. 1913-1965.
2. Filippov, L.P. Prognozirovanie teplofizicheskih svoystv zhidkostey i gazov / L.P. Filippov. - M.: Energoatomizdat, 1988. - 168 s.
3. Meyra, A.G. Universal behavior of the enthalpy of vaporization: an empirical equation / A.G. Meyra, V.A. Kuz, G.J. Zarragoicoechea // Fluid Phase Equilibria. - 2004. - № 218. - P. 205-207.
4. Esina, Z.N. Matematicheskoe modelirovanie fazovogo perehoda zhidkost' - tverdoe / Z.N. Esina, M.R. Korchuganova, V.V. Murashkin // Vestnik Tomskogo gosudarstvennogo universiteta. Upravlenie, vychislitel'naya tehnika i informatika. - 2011. - № 3 (16). - S. 13−23.
5. A. s. 2012618394 Rossiyskaya Federaciya. Phase Chart Eutectic and Azeotropic System (PCEAS) / Z.N. Esina, V.V. Murashkin, M.R. Korchuganova. - № 2012616324; zayavl. 25.07.2012; reg. 17.09.2012.
6. Ogorodnikov, S.K. Azeotropnye smesi: spravochnik / S.K. Ogorodnikov, T.M. Lesteva, V.B. Kogan; pod red. prof. V.B. Kogana. - L.: Himiya, 1971. - 849 s.
